Hugendubel.info - Die B2B Online-Buchhandlung 

Merkliste
Die Merkliste ist leer.
Bitte warten - die Druckansicht der Seite wird vorbereitet.
Der Druckdialog öffnet sich, sobald die Seite vollständig geladen wurde.
Sollte die Druckvorschau unvollständig sein, bitte schliessen und "Erneut drucken" wählen.
E-BookPDFDRM AdobeE-Book
422 Seiten
Englisch
Elsevier Science & Techn.erschienen am22.10.2013
Strained Organic Molecule, Volume 38 considers the vast field of strained organic molecules. The book discusses energy and entropy; cyclopropane and cyclobutane; and unique strained groupings or building blocks. The text also describes the aesthetics, rearrangements, and topology of polycycles; kinetic and thermodynamic stability; and tetrahedral tetracoordinate carbon. The inverted tetrahedra, propellanes, buttaflanes, and paddlanes; planar methane and its derivatives; and five- and six-coordinaste carbon are also considered. Chemists will find the book invaluable.mehr

Produkt

KlappentextStrained Organic Molecule, Volume 38 considers the vast field of strained organic molecules. The book discusses energy and entropy; cyclopropane and cyclobutane; and unique strained groupings or building blocks. The text also describes the aesthetics, rearrangements, and topology of polycycles; kinetic and thermodynamic stability; and tetrahedral tetracoordinate carbon. The inverted tetrahedra, propellanes, buttaflanes, and paddlanes; planar methane and its derivatives; and five- and six-coordinaste carbon are also considered. Chemists will find the book invaluable.
Details
Weitere ISBN/GTIN9781483217956
ProduktartE-Book
EinbandartE-Book
FormatPDF
Format HinweisDRM Adobe
Erscheinungsjahr2013
Erscheinungsdatum22.10.2013
Seiten422 Seiten
SpracheEnglisch
Artikel-Nr.3137758
Rubriken
Genre9200

Inhalt/Kritik

Inhaltsverzeichnis
1;Front
Cover;1
2;Strained Organic Molecules;4
3;Copyright Page;5
4;Table of Contents;6
5;Preface;10
6;CHAPTER 1. Energy and Entropy;16
6.1;1.A
Reference States and Reference Books;16
6.2;1.B
Origin of Molecular Strain;28
6.3;1.C
Thermodynamics and Symmetry;36
6.4;1.D
Potential Energy Curves and Zero-Point Energy;39
7;CHAPTER 2. Cyclopropane and Cyclobutane;44
7.1;2.A Conceptual Models for the Bonding in Cyclopropane;44
7.2;2.B Selected Reactions of Cyclopropanes;61
7.3;2.C Cyclobutane;70
8;CHAPTER 3. Unique Strained Groupings or Building Blocks;79
8.1;3.A Cycloalkanes;80
8.2;3.B Bicyclic, Spirocyclic, and Bridged Hydrocarbons;85
8.3;3.C Tetrahedrane;100
8.4;3.D Strained Alkenes: Molecules Lacking Torsional Strain;105
8.5;3.E Torsionally Distorted
p Bonds;123
8.6;3.F "Bredt Compounds9' and Cyclic
Allenes;141
8.7;3.G Cycloalkynes, Benzyne, and Cyclocumulenes;148
8.8;3.H Distorted Aromatic Rings;154
9;CHAPTER 4. Polycycles: Aesthetics, Rearrangements, and Topology;193
9.1;4.A Adamantanes and Higher Homologues;193
9.2;4.B Iceane;212
9.3;4.C Miscellaneous Acid-Catalyzed Rearrangements;214
9.4;4.D Strained Molecules of Formula (CH)n;218
9.5;4.E Additional Polycyclic Molecules;230
9.6;4.F Molecular Topology;235
10;CHAPTER 5. Kinetic and
Thermodynamic Stability;240
10.1;5.A Introduction;240
10.2;5.B Orbital Symmetry and Stabilities of Benzene Valence Isomers;243
10.3;5.C Transition Metals and Strained Carbocyclic Molecules;260
10.4;5.D Strained Heterocyclic Molecules;292
10.5;5.E Substituted Derivatives of Strained Molecules;340
11;CHAPTER 6. A Potpourri of Pathologies;357
11.1;6.A When is Tetracoordinate Carbon Tetrahedral?;357
11.2;6.B Inverted Tetrahedra, Propellanes, Buttaflanes, and Paddlanes;358
11.3;6.C Planar Methane and Its Derivatives;384
11.4;6.D Five- and Six-Coordinate Carbon;390
12;Addendum;401
13;Index;407
14;ORGANIC CHEMISTRY;422mehr

Autor