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Donor-Acceptor Cyclopropanes in Organic Synthesis

BuchGebunden
464 Seiten
Englisch
Wiley-VCHerschienen am20.03.20241. Auflage
Facilitate milder, simpler reactions in organic synthesis with this cutting-edge family of building blocks Donor-Accepted Cyclopropanes, or DACs, have attracted a resurgence of interest from organic chemists in recent decades for their role in facilitating various reactions such as cycloadditions, annulations, ring-opening and enantioselective transformations. The structural arrangement of DACs leads to milder, simpler reaction conditions, which have made them indispensable for a range of fundamentally and industrially important processes. Donor-Acceptor Cyclopropanes in Organic Synthesis covers comprehensively the chemistry and applications of this compound class. The result is an invaluable guide for any researcher looking to bring DACs to bear in their own areas of research or development. Readers will also find: A brief introduction of the history and reactivity of DACsDetailed discussion of reactions including Lewis acid-catalyzed cycloadditions, metal-free activation, asymmetric transformations, organocatalysis, and many moreApplication of DACs in natural product synthesis and pharmaceutical/agrochemical research Donor-Acceptor Cyclopropanes in Organic Synthesis is ideal for organic chemists, experts in catalysis, pharmaceutical researchers, and any other scientists interested in facilitating milder, simpler reactions.mehr
Verfügbare Formate
BuchGebunden
EUR149,00
E-BookPDF2 - DRM Adobe / Adobe Ebook ReaderE-Book
EUR133,99
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EUR133,99

Produkt

KlappentextFacilitate milder, simpler reactions in organic synthesis with this cutting-edge family of building blocks Donor-Accepted Cyclopropanes, or DACs, have attracted a resurgence of interest from organic chemists in recent decades for their role in facilitating various reactions such as cycloadditions, annulations, ring-opening and enantioselective transformations. The structural arrangement of DACs leads to milder, simpler reaction conditions, which have made them indispensable for a range of fundamentally and industrially important processes. Donor-Acceptor Cyclopropanes in Organic Synthesis covers comprehensively the chemistry and applications of this compound class. The result is an invaluable guide for any researcher looking to bring DACs to bear in their own areas of research or development. Readers will also find: A brief introduction of the history and reactivity of DACsDetailed discussion of reactions including Lewis acid-catalyzed cycloadditions, metal-free activation, asymmetric transformations, organocatalysis, and many moreApplication of DACs in natural product synthesis and pharmaceutical/agrochemical research Donor-Acceptor Cyclopropanes in Organic Synthesis is ideal for organic chemists, experts in catalysis, pharmaceutical researchers, and any other scientists interested in facilitating milder, simpler reactions.
Details
ISBN/GTIN978-3-527-34987-6
ProduktartBuch
EinbandartGebunden
Verlag
Erscheinungsjahr2024
Erscheinungsdatum20.03.2024
Auflage1. Auflage
Seiten464 Seiten
SpracheEnglisch
Gewicht960 g
Illustrationen29 Tabellen
Artikel-Nr.54741486

Inhalt/Kritik

Inhaltsverzeichnis
Preface 1) Introduction to the Chemistry of Donor-Acceptor Cyclopropanes: A Historical and Personal Perspective 2) Understanding Reactivity of Donor-Acceptor Cyclopropanes: Structural and Electronic Analysis 3) Cycloaddition and Annulation Reactions of Donor-Acceptor Cyclopropanes 4) Activation of Donor-Acceptor Cyclopropanes under Covalent Organocatalysis: Enamine, Iminium, NHC and Phosphine Catalysis 5) Ring-Opening 1,3-Difunctionalization of Donor-Acceptor Cyclopropanes 6) Molecular Rearrangements in Donor-Acceptor Cyclopropanes 7) Donor-Acceptor Cyclopropanes with Amino Group as Donor 8) Chemistry of Cyclopropyl Monocarbonyls 9) Chemistry of Aroyl- and Nitro-substituted Donor-Acceptor Cyclopropanes 10) Metal-free Activation of the Donor-Acceptor Cyclopropanes: Thermal Reactions, Protic Acids and Bases 11) Asymmetric Catalytic Activation of Donor-Acceptor Cyclopropanes 12) Donor-Acceptor Cyclopropanes in Natural Product Synthesismehr

Schlagworte

Autor

P. Banerjee has obtained his Doctoral degree from National Chemical Laboratory (NCL) under the supervision of Prof. Ganesh Pandey, Pune, and later worked with Prof. Gais at RWTH-Aachen, Germany as DFG postdoctoral fellow from 2005 to 2007. Then he moved to Purdue University, USA, where he worked with Prof. Fuchs before joining IIT Ropar as an assistant professor in 2010 at the Department of chemistry. He was promoted to associate professor in 2016. He has extensive research experience in pericyclic reactions with particular emphasis on cycloaddition reactions, asymmetric catalysis, and synthesis of medicinally significant molecules. In his independent research carrier, he has also worked extensively on the reactivity of different strained rings towards cycloaddition reactions to synthesize pharmaceutically important heterocyclic compounds.

A. T. Biju received his PhD (2006) under the guidance of Dr Vijay Nair at the CSIR-NIIST (Formerly RRL), Trivandrum, India. Subsequently, he has been a post-doctoral fellow with Prof. Tien-Yau Luh (National Taiwan University) and an AvH fellow with Prof. Frank Glorius (WWU Münster, Germany). In June 2011, he began his independent research career at the CSIR-NCL, Pune. Since June 2017, he has been an Associate Professor in the Department of Organic Chemistry, Indian Institute of Science, Bangalore. His research focuses on the development of transition-metal-free carbon-carbon and carbon-heteroatom bond-forming reactions using aryne chemistry and NHC organocatalysis, and their application in organic synthesis. He is the Editor of J. Heterocyclic Chem., and the Advisory Board of Org. Chem. Front. And Asian J. Org. Chem.
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Herausgegeben:Banerjee, Prabal