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d-Orbitals in the Chemistry of Silicon, Phosphorus and Sulfur

BuchKartoniert, Paperback
222 Seiten
Englisch
Springererschienen am08.03.2012Softcover reprint of the original 1st ed. 1977
In recognition of this and to show the wayan appendix of recent results and interpretation has been included where an alteration in viewpoint on some of the material treated in the text has been necessitated by developments in the most recent literature.mehr
Verfügbare Formate
BuchKartoniert, Paperback
EUR106,99
E-BookPDF1 - PDF WatermarkE-Book
EUR96,29

Produkt

KlappentextIn recognition of this and to show the wayan appendix of recent results and interpretation has been included where an alteration in viewpoint on some of the material treated in the text has been necessitated by developments in the most recent literature.
Details
ISBN/GTIN978-3-642-46344-0
ProduktartBuch
EinbandartKartoniert, Paperback
Verlag
Erscheinungsjahr2012
Erscheinungsdatum08.03.2012
AuflageSoftcover reprint of the original 1st ed. 1977
ReiheReactivity and Structure: Concepts in Organic Chemistry
Seiten222 Seiten
SpracheEnglisch
Gewicht414 g
IllustrationenVIII, 222 p.
Artikel-Nr.18234448

Inhalt/Kritik

Inhaltsverzeichnis
I. Introduction - d?-vs. d? Bonding.- II. Theoretical Basis for d-Orbital Involvement.- A. Geometry of Bonding Orbitals.- B. Size of d-Orbitals.- C. Effect of Electronegative Ligands.- D. Energies of d-Orbitals.- E. Alternate Explanations for d? and d? Bonding.- F. d? Delocalized Bonding.- III. Physical Properties Related to dp-? Bonding.- A. Bond Lengths and Angles.- B. Infrared Spectra.- C. NMR and Related Indices.- D. UV, ESR and Dipole Moments.- IV. The Effects of dp-? Bonding on Chemical Properties and Reactivity.- A. Acidity-Basicity.- B. Electrophilic Aromatic Substitution.- C. Alpha-Sulfonyl and -Sulfinyl Carbanions.- D. Alpha-Thio Carbanions.- E. Thiazolium Ylides.- F. Addition to Conjugated Carbon-Carbon Double Bonds.- G. Survey of Relevant Articles Sections IV A-IV F.- V. Pentacovalency.- A. The Pentavalent State in Organic Chemistry.- B. dp-? Bonding in Phosphate Hydrolysis.- C. Pentavalent Intermediates in Phosphate Hydrolysis.- D. Pentacoordinate Sulfur Intermediates.- E. Pentacoordinate Silicon Intermediates.- F. Synthetic Applications of Pentacoordinate Intermediates.- VI. References.- VII. Appendix of Recent Results and Interpretations.- VIII. Index of Authors and References.- IX. Index of Reference - Page Citations.- X. Subject Index.mehr