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Base-Metal Catalysis 1

BuchGebunden
692 Seiten
Englisch
Thiemeerschienen am07.12.2022
Recent advances in catalytic methods based on earth-abundant metals are discussed. Catalysis with earth-abundant metals, often referred to as base metals, is having a transformative impact on synthetic chemistry. Research in this area is driven not only by the common interest in the sustainability of chemical synthesis but also by the vast opportunity to discover and develop novel reaction chemistry that is not attainable with rare and precious metal catalysts. This work provides representative developments in base-metal catalysis, specifically catalysis with 3d-transition metals, in a format suitable for practitioners of organic synthesis.Volume 1 is focused on recent advances in copper and nickel catalysis, including Ullmann-type coupling, reductive coupling and cross-coupling reactions, CH activation and functionalization, and alkene hydrofunctionalization and difunctionalization. Methods for the installation of important functional groups such as trifluoromethyl and carboxyl, and for the aerobic oxidation of alcohols are also covered.mehr
Verfügbare Formate
BuchGebunden
EUR2.999,99
EUR2.999,99

Produkt

KlappentextRecent advances in catalytic methods based on earth-abundant metals are discussed. Catalysis with earth-abundant metals, often referred to as base metals, is having a transformative impact on synthetic chemistry. Research in this area is driven not only by the common interest in the sustainability of chemical synthesis but also by the vast opportunity to discover and develop novel reaction chemistry that is not attainable with rare and precious metal catalysts. This work provides representative developments in base-metal catalysis, specifically catalysis with 3d-transition metals, in a format suitable for practitioners of organic synthesis.Volume 1 is focused on recent advances in copper and nickel catalysis, including Ullmann-type coupling, reductive coupling and cross-coupling reactions, CH activation and functionalization, and alkene hydrofunctionalization and difunctionalization. Methods for the installation of important functional groups such as trifluoromethyl and carboxyl, and for the aerobic oxidation of alcohols are also covered.
Details
ISBN/GTIN978-3-13-245380-7
ProduktartBuch
EinbandartGebunden
Verlag
ErscheinungsortStuttgart
ErscheinungslandDeutschland
Erscheinungsjahr2022
Erscheinungsdatum07.12.2022
ReiheScience of Synthesis
Seiten692 Seiten
SpracheEnglisch
Gewicht1468 g
Artikel-Nr.51292513

Inhalt/Kritik

Inhaltsverzeichnis
1 Introduction1.1 Modern Ullmann-Type Couplings1.2 Copper(I) Hydride Catalyzed Transformations1.3 Copper-Catalyzed Alkene Difunctionalization1.4 Copper-Catalyzed C-H Functionalization via Radicals1.5 Copper-Catalyzed Directed C-H Functionalization1.6 Copper-Catalyzed Acidic C-H Functionalization1.7 Copper-Catalyzed/Mediated Trifluoromethylation and other Fluoroalkylations1.8 Copper-Catalyzed Aerobic Oxidation of Alcohols1.9 Base-Metal-Catalyzed Carboxylation Using Carbon Dioxide1.10 Nickel-Catalyzed Cross-Electrophile Coupling Reactions1.11 Nickel-Catalyzed Enantioselective Reductive Cross-Coupling Reactions1.12 Nickel-Catalyzed Alkene Dicarbofunctionalization1.13 Nickel-Catalyzed Cross Coupling Involving Alkenes1.14 Nickel-Catalyzed Directed C-H Functionalization1.15 Nickel-Catalyzed Nondirected C-H Functionalization1.16 Nickel-Catalyzed Bond Activation for Functional-Group Shuttling1.17 Nickel-Catalyzed Cross Coupling via C-O and C-N Activationmehr